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Home/Carboxylic acid

Preparation of carboxylic acid by ( carbonation of Grignard reagent, Hydrolysis of Nitriles, oxidation of alcohols and aldehydes , oxidative cleavage of Alkene,

Question#1

Which of the acids cannot be prepared by Grignard reagent [MH CET 2004]

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Question#2

How will you convert butan-2-one to propanoic acid [IIT-JEE (Screening) 2005]

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Question#3

R CH 2CH 2OH can be converted into . RCH 2CH 2COOH The correct sequence of the reagents is [AIIMS 1997]

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Question#4

X is heated with soda lime and gives ethane. X is [AFMC 2005]

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Question#5

The end product B in the sequence of reactions

\( R-X \xrightarrow{CN-} A \xrightarrow{NaOH} B \)  is [CPMT 1985]

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Question#6

Acetic acid will be obtained on oxidation of [J & K 2005]

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Question#7

Toluene is oxidised to benzoic acid by [BHU 2004; CPMT 1985]

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Question#8

The compound X, in the reaction, is

\( X \xrightarrow{CH3MgI} Y \xrightarrow{Hydrolysis} Mg(OH)I + CH_3COOH \) [Pb. CET 2003]

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Question#9

Primary aldehyde on oxidation gives [DPMT 20004]

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Question#10

CO2 on reaction with ethyl magnesium bromide gives [BHU 1983]

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Question#11

The acid formed when propyl magnesium bromide is treated with carbon dioxide is [CPMT 1982, 84, 86; Pb. PMT 1998]

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Question#12

\( (CH_3)_2CO \xrightarrow[KCN]{HCl} A \xrightarrow[H3O+]{\Delta} B \) In the above sequence of reactions A and B are [CPMT 2000]

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Question#13

Which of the following gives benzoic acid on oxidation [CBSE PMT 1996]

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Question#14

When benzyl alcohol is oxidized with , KMnO4 the product obtained is [SCRA 1991]

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Question#15

Which of the following on hydrolysis forms acetic acid [BHU 1997]

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Question#16

\( C_2H_2 \xrightarrow[H2SO4]{HgSO4} A \xrightarrow{[O]} B \) ,  B is [CBSE PMT 1991; BHU 1995]

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Question#17

\( CO + NaOH \rightarrow ? \) [CPMT 1997; KCET 1999]

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Question#18

Acetic acid is manufactured by the fermentation of [CPMT 1985]

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Question#19

Acetic acid is obtained when [NCERT 1975; CPMT 1977]

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Question#20

The reduction of a nitrile produced a compound of formula C3H7NH2. Which one of the following compound would be produced if the same nitrile was hydrolyzed by heating with Dil.HCl ? NUMS2016

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Question#21

Hydrolysis of Alkane nitriles produces NUMS2020

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Question#22

Methyl cyanide, on boiling with Mineral acids or alkalis, yield: MDCAT2013 

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Question#23

When CH3CH2OH is oxidized in the presence of K2Cr2O7 and H2SO4 the product formed is MDCAT2012.

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Question#24
\( CH_3CN + HCl \rightarrow A + B \) in presence of water in the above reaction A and B are MDCAT2011
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Question#25
Hydrolysis of cyano group by an aqueous acid results into MDCAT2010
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Categories
1.    Introduction To Fundamental
         Atomic Mass
         Empirical formula
         Molecular Formula
         Concept of Mole
         Stoichiometry
         Limiting Reactant
         Percentage yield
2.    Atomic Strcuture
         Constituents of atom
         Properties of canal rays
         Rutherford Model
         Planks Theory
         Spectrum
         Bohr Model
         Hydrogen Spectrum
         de Broglie relation
         Uncertainty principle
         Quantum Number
         Electronic configuration
4.    Liquids
         Intermolecular forces
         hydrogen Bonding
         Evaporation
         Vapor Pressure
5.    Solids
         Types of Solids
         Ionic Solids
         Covalent Solids
         Molecular Solids
         Metallic solids
         Unit Cell
         Crystal System
7.    Reaction kinetics
10.    chemical Bonding
         Valency
         Octate Rule
         Ionization Energy
         Electron affinity
         Electronegativity
         Ionic Bond
         Covalent Bond
         Polarization
         Coordinate covalent Bond
         Sigma and pi Bond
         Hydrogen Bond
         VSEPR theory
         VBT
         Hybridization
         MOT
         Dipole moment
14.    Chemistry Of Hydrocarbons
17.    Alkyl halides
         IUPAC system
         SN1 & SN2
         E1 & E2
         Nucleophile and Base
20.    Macromolecules