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Home/Alkyl halides

Nucleophile and Base

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Question#1

Which alkyl halide ion has the capacity to act as both very good nucleophile and good leaving group in nucleophilic substitution reaction SET2019 

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Question#2

In elimination reaction, alcoholic KOH is used. OH- in this case will act as MDCAT2017

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1.    Introduction To Fundamental
         Atomic Mass
         Empirical formula
         Molecular Formula
         Concept of Mole
         Stoichiometry
         Limiting Reactant
         Percentage yield
2.    Atomic Strcuture
         Constituents of atom
         Properties of canal rays
         Rutherford Model
         Planks Theory
         Spectrum
         Bohr Model
         Hydrogen Spectrum
         de Broglie relation
         Uncertainty principle
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         n+l , Auf-Bau, Pauli and Hund's Rule
         Quantum mechanical model/ Schrodinger wave equation
3.    Gases
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         Boyle's Law
         Charles Law and Absolute Scale of temperature
         Avogadro's Hypothesis
         Ideal gas equation
         Daltons Law of Partial pressure
         kinetic Molecular Theory of gases
         Ideal and Real Gases
         van Der Waals Equation
4.    Liquids
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         hydrogen Bonding
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         Application of Law of Mass equilibrium (law of mass action)
         Applications and units of equilibrium constant
         Relation between kp and kc
         Factor effecting balance of chemical equilibrium (Le chatelier's principle)
         Common ion effect
         Ph
         Buffers
         Solubility Product
         Lowry-Bronsted acid base concept
7.    Reaction kinetics
         Rate of reaction
         Velocity constant or rate constant( K)
         rate Laws
         order of reaction
         Zero order reactions
         First order reactions
         Second order Reactions
         Third order reactions
         Half life of reaction
         How to determine rate of reaction.
         Ea(activation energy)
         collision theory
         transition state theory
         Arrhenius Equation
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8.    Thermochemistry
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         First Law of thermodynamics
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         experimental determination of the heat of reaction
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9.    Electrochemistry
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10.    chemical Bonding
         Valency
         Octate Rule
         Ionization Energy
         Electron affinity
         Electronegativity
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         VSEPR theory
         VBT
         Hybridization
         MOT
         Bond features (Bond length,Bond energy and Bond angle)
         Dipole moment
11.    s and p block Elements
         Demarcation of periodic Table
         Periodic properties (Atomic radius, I.E, E.A, E.N, MP, B.P, O.S, Electrical conductance, Hydration energy )
         Reactions of group 1 elements( Alkali metals)
         Reactions of Group-llA (Alkaline earth elements)
         Trend in solubility of nitrates, hydroxides, oxides, sulphates and carbonates of G_IAand G-lIA elements
         Effect of heat on hydroxides, carbonates and nitrates of G-1 and G-ll elements
         Reaction of Period 3 element with water, oxygen and chlorine
12.    Transition Elements
         Introduction
         General Features (Atomic radius, Electronic structure, Binding energy, Variable oxidation state, paramagnetic and diamagnetic behavior, Color complexes)
         Components of Complex Compounds
         Nomenclature of complex compounds
         Shapes of complex ions
13.    Fundamental Concepts of Organic Chemistry
         Organic chemistry and organic compounds
         The Special features of carbon chemistry
         Classification of organic compounds based on carbon skeleton
         Structural Isomerism in organic compounds
         Functional Groups
         Stereo Isomerism
         Hybridization
14.    Chemistry Of Hydrocarbons
         Introduction
         IUPAC Naming
         Physical Properties of Alkane Alkene and Alkynes
         Preparations Of Alkanes
         Preparation of alkenes
         Preparations Of alkynes
         Reactivity Of Alkanes
         Reactivity Of alkene
         Reaction Of Alkyne
         Acidity Of terminal Alkynes
         Reactivity comparison of Hydrocarbons
15.    Benzene
         IUPAC Naming and classification
         Physical properties of benzene
         Molecular orbital Aspects
         Resonance energy and Stability of benzene
         Preparation of benzene
         Reactivity and reactions ( catalytic Hydrogenation, Oxidation, Nitration, Halogenation, Sulphonation )
         Fridel Craft Alkylation and Acylation
         Substituent effects
16.    Alcohol and phenols
         Naming and Designation Of Alcohols
         Physical properties of Alochols
         Preparations of Alcohols
         Reactivity of Alcohols
         Predicting Relative acidity of alcohols
         iodoform test
         Lucas test
         Naming of aromatic hydroxy groups (phenol)
         Physical properties of phenol
         Preparation Of phenols
         Reactions of phenols
         Acidity of Phenols
         Identification test for Phenol
17.    Alkyl halides
         IUPAC system
         Preparations of alkyl halides
         Reactivity of Alkyl halides
         SN1 & SN2
         E1 & E2
         Nucleophile and Base
         Substrate and Leaving group
         Organomettalic Compound (Grignard Reagent)
18.    Aldehyde and ketones
         Nomenclature and structure of Aldehyde and ketones
         preparation of Ald & Ket
         Relative Reactivity of carbonyls
         Addition Of HCN and NaHSO3 to Carbonyls
         Aldol condensation
         Cannizaro's reaction
         Addition Elimination reactions
         oxidation reduction Reactions of carbonyls
         Identifications Reactions
19.    Carboxylic acid
         Nomenclature
         Physical properties
         Preparation of carboxylic acid by ( carbonation of Grignard reagent, Hydrolysis of Nitriles, oxidation of alcohols and aldehydes , oxidative cleavage of Alkene,
         Reaction involving H-atom of the carboxylic acid
         Reaction involving the OH-group of carboxylic acid
         Reaction involving Carboxyl group (-COOH)
         Acidity
         Tests for carboxylic Group
         Preparation and Reactions of carboxylic acid derivatives
20.    Macromolecules