Question#1
Propanone can be prepared from propyne by MDCAT2023
Question#2
\( CH3COOH \) is reacted with \( CH \equiv CH \) in presence of , Hg++ the product is [DPMT 2004; BHU 1998]
\( CH \equiv CH + CH_3-COOH \xrightarrow{Hg++} H_2C=CH - OCOCH_3 +CH_3COOH \rightarrow CH_3-CH (O-COCH_3 )_2 \)
Question#3
Ozonolysis of acetylene gives [RPMT 1999]
Question#4
Which of the following is used to distinguish ethylene and acetylene [MP PET 20CPMT 1977; NCERT 1973]
Question#5
KMnO4 will oxidize acetylene to [CPMT 1999]
Question#6
Which of the following catalyst is used in the polymerisation of \( CH \equiv CH \ to \ C_6H_6 \) [CPMT 1999]
Question#7
When treated with ammoniacal cuprous chloride, which one among the following forms copper derivative [CBSE PMT 1989; MP PMT 1993]
Question#8
Propyne on polymerisation gives [CPMT 1999, 2002]
Question#9
When propyne reacts with aqueous H2 SO4 in the presence of HgSO4 , the major product is [IIT-JEE 1983; AFMC 1991; KCET 1993]
Question#10
When acetylene reacts with HCl in the presence of HgCl2 , the product is [MNR 1985; MP PET 1996; UPSEAT 2000]
Question#11
A gas decolourises bromine in CCl 4 and forms a precipitate with ammoniacal silver nitrate. The gas is [EAMCET 1998]
Question#12
The product(s) obtained via oxymercuration ( HgSO4 + H2 SO4 ) of 1-butyne would be [IIT-JEE 1999]
Question#13
An unknown compound A has a molecular formula C4 H6 When A is treated with an excess of Br2 a new substance B with formula C4 H6Br4 is formed. A forms a white precipitate with ammoniacal silver nitrate solution. A may be [MP PET/PMT 1998]
Question#14
The compound C3H4 has a triple bond, which is indicated by its reaction with [MP PMT 1999]
Question#15
What is the end product of the following sequences of operations [CPMT 1978; MP PMT 1996]
\( CaC_2 \xrightarrow{H2O} A \xrightarrow[Hg++]{dil.H2SO4} B \xrightarrow[H2]{Ni} C \)
\( CaC_2 \xrightarrow{H2O} HC \equiv CH \xrightarrow[Hg++]{dil.H2SO4} CH_3-CHO \xrightarrow[H2]{Ni} CH_3-CH_2-OH \)
Question#16
Which of the following will be the final product when C2H2 reacts with HCl [DPMT 1984; AFMC 1982; Bihar MEE 1982]
\( HC \equiv CH + HCl \rightarrow CH_2=CHCl + HCl \xrightarrow{Markovni Rule} CH_3-CHCl_2 \)
Question#17
When propyne is treated with dilute H2SO4 and HgSO4 , the major product is [CEE 2002]
Question#18
When propyne is treated with dilute H2SO4 and HgSO4 , the major product is [CEE 2002]
Question#19
Products of the following reaction
\( CH_3-C \equiv C-CH_2- CH_3 \xrightarrow[Hydrolysis]{O3} \) are [CBSE PMT 2005]
Question#20
Which is the most suitable reagent among the following to distinguish compound (iii) from rest of the compounds [CBSE PMT 1989]
(i) \( CH_3 - C \equiv C - CH_3 \)
(ii) \( CH_3 - CH_2 - CH_2 - CH_3 \)
(iii) \(CH_3 - CH_2 - C \equiv CH \)
(iv) \( CH_3 -CH = CH_2 \)
Question#21
The product formed when acetylene is passed through red hot tube is [BHU 1989; RPMT 2003]
Question#22
The product formed when acetylene is passed through red hot tube is [BHU 1989; RPMT 2003]
Question#23
1-butyne reacts with cold alkaline KMnO4 to produce [AIIMS 1997]
Question#24
What is suitable catalyst for the reaction given below ? ETEA2016
\( HC\equiv CH + H_2O \longrightarrow CH_2=CH-OH \longrightarrow CH_3-CHO \)
Kucherov's reaction
\( HC \equiv CH +H_2O \rightarrow CH_2=CH-OH \xrightarrow{tautomerism} CH_3-CO-H \)
Question#25
\( CH_3-CH_2-C \equiv CH + H_2O \longrightarrow \ ? \) ETEA2016 med